In your web.config, add the following lines.
<system.web>
<webServices>
<protocols>
<add name="HttpGet" />
<add name="HttpPost" />
</protocols>
</webServices>
</system.web>
Code level:
Add the following before your webservice method.
[ScriptMethod(UseHttpGet = true)]
Example:
[ScriptMethod(UseHttpGet = true)]
[WebMethod(Description = "webservice description.")]
public List GetItems()
{
// more codes
}